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Ketone formation, as in the original Roelen experiment, is significant only with ethylene. Hydroformylation gained substantial industrial importance in the manufacture of butyraldehyde and certain alcohols (see Section 7.1.3). Because of its practical significance, commercial applications were followed by substantial research efforts 2- 16 resulting in a good understanding of the chemistry of the reaction. All Group VIII metals, as well as Mn, Cr, and Cu, exhibit some activity in hydroformylation. 6,11 Cobalt, the catalyst in the original discovery, is still used mainly in industry; rhodium, introduced later, is one of the most active and studied catalysts. The metal catalysts may be applied as homogeneous soluble complexes, heterogenized metal complexes, or supported metals. [COH(CO)4], formed in situ when cobalt metal or cobalt(II) salts are reacted with synthesis gas at elevated temperature under pressure, is the active species in the cobalt-catalyzed reaction. 14,17,18 It is also capable of stoichiometric

more sites, and nally Globus Toolkit services can be used as the bridge between them. In fact, Figure 11.2 can serve as a simpli ed diagram for many emerging grids, such as the USCMS Test bed Grid [51], established for the purpose of high-energy physics event reconstruction. Another example is the European Union DataGrid [52] project s Grid Resource Broker, which utilizes Condor-G as its job submission service [53].

g(x) =

The contents of the x-ray tube are in a vacuum so that there are no gas particles to impede the ow of the electrons.

You might think you can use the auto-correction feature to have InDesign substitute special characters for codes you enter, to save the hassle of memorizing the keyboard shortcuts or using the Glyphs panel. But you can t: InDesign won t let you enter special characters in the Correction field after you click the Add button. That means, for example, you cannot have InDesign change -- to an em dash ( ), or change (r) to using this feature. 15 explains how to work with InDesign s spell-checking capabilities.

Proof [203, p. 2621 We will show that bursts of different lengths reside in different cosets, so they can be employed as coset leaders and form correctable error patterns. Let a ( x ) and b(x) be polynomials of degree 1 1 - 1 and 12 - 1, representing bursts of length 11 and 12, respectively, a(x>= 1 alx a2x2 . . . a', - 2 x ' 1 - ~ x'1-l

Some products may be bad in the sense that customers purchase them and never purchase anything else. This suggests the question: How many products

endosymbiont, Wolbachia, in the X chromosome of the insect host (Kondo et al., 2002); and (iii) the presence of bacteriophytochrome genes in the genome of the fungus, Neurospora crassa (Galagan et al., 2003). The means by which the above genes were exchanged remains largely unknown. Nonetheless, such HGT mechanisms are vital in contributing to biological diversity. The impact of HGT on both the form and validity of the tree of life has been hotly debated for many years (e.g., Doolittle, 1999; Gogarten et al., 2002; Lawrence and Hendrickson, 2005). A version of the tree of life showing HGT is shown in Figure 5.22. Another major trait for assessing biotic diversity is cell size (e.g., physical dimensions, shape, surface-to-volume ratio). This trait has major implications for the rate of material uxes both within cells and between cells and their habitats. Ultimately cell size and shape re ect selective pressures over evolutionary history. Figure 5.23 presents a comparison of the size of known microorganisms (Ward and Fraser, 2005).

Figure 14.37 Cyclic voltammogram of boron-doped single crystalline diamond electrode in 0.1-M H2 SO4 electrolyte. A voltammogram of technical platinum is shown for comparison. Also shown are the standard potenials of water dissociation

Typical designs will have many repeated assets. You may have a navigation bar that contains repeating backgrounds for buttons or a planned fillable form with repeated boxes representing the backgrounds of the form fields. While standard practice in Illustrator is to simply copy these assets, Catalyst contains the ability to take an object, convert it to a component, and reuse that component as often as needed. In fact, you will want to avoid repeatedly defining components for artwork that is the same, as it needlessly bloats the file size of the final Flex project and makes updating and maintaining the application more difficult. Therefore, mark any assets that you are copying in Illustrator to make it clear that they do not need to be redefined.